{"id":10501,"date":"2026-10-22T14:30:09","date_gmt":"2026-10-22T14:30:09","guid":{"rendered":"https:\/\/lumomat.fr\/?p=10501"},"modified":"2026-10-22T14:47:59","modified_gmt":"2026-10-22T14:47:59","slug":"thesis-defense-sara-helis-vendredi-6-novembre-2026","status":"publish","type":"post","link":"https:\/\/lumomat.fr\/eng\/thesis-defense-sara-helis-vendredi-6-novembre-2026\/","title":{"rendered":"Thesis Defense Sara Helis \u2013 Vendredi 6 Novembre 2026"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"10501\" class=\"elementor elementor-10501\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-9ff58b2 e-flex e-con-boxed e-con e-parent\" data-id=\"9ff58b2\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-df26bf7 elementor-widget elementor-widget-text-editor\" data-id=\"df26bf7\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t\t\t\t\t\t<p>\ud83c\udf93 [THESIS DEFENSE] &#8211; Sara Helis will defend her PhD thesis: <br \/>\ud83d\udd2c \u201cTailoring Functional Molecular Interfaces through Controlled Aryldiazonium Electrografting for Enhanced Reactivity\u201d <br \/>\ud83d\udcc5 Friday 6 November 2026 at 09:15 &#8211; Facult\u00e9 des Sciences d\u2019Angers \/ Amphi L004 This thesis is labelled by EUR LUMOMAT<!-- notionvc: 328bfcb0-a77a-4ff6-8c76-359513d518ee --><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-066278d e-flex e-con-boxed e-con e-parent\" data-id=\"066278d\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-72ae12b elementor-widget elementor-widget-text-editor\" data-id=\"72ae12b\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t\t\t\t\t\t<p>This thesis is supervised by Prof. Tony Breton \u2013 MOLTECH-Anjou &#8211; Universit\u00e9 d\u2019Angers<\/p><p>Examining Committee :<br \/>\u2796 <strong>Dr. Christophe Bucher<\/strong> \u2013 CNRS\/ENS Lyon \u2013 Reviewer<br \/>\u2796 <strong>Dr. Jalal Ghilane<\/strong> \u2013 CNRS\/Universit\u00e9 Paris-Cit\u00e9 \u2013 Reviewer<br \/>\u2796 <strong>Dr. Sheena Louisia<\/strong> \u2013 CNRS\/Sorbonne Universit\u00e9 \u2013 Examiner<br \/>\u2796 <strong>Dr. Anne de Poulpiquet<\/strong> \u2013 Aix-Marseille Universit\u00e9 \u2013 Examiner<br \/>\u2796 <strong>Dr. Jon Ustarroz<\/strong> \u2013 Universit\u00e9 Libre de Bruxelles \u2013 Examiner<br \/>\u2796 <strong>Dr. Jean-Marc No\u00ebl<\/strong> \u2013 CNRS\/Universit\u00e9 Paris-Cit\u00e9 \u2013 Invited member<\/p><p>[\ud83d\udcc4 ABSTRACT]<\/p><p>The immobilization of functional molecules on electrodes provides a route toward molecular interfaces with tunable properties and reactivity. This thesis investigates aryldiazonium electrografting to understand and control film formation and its influence on the properties of immobilized species.<\/p><p>Using 4-nitrobenzenediazonium as a model system, the competitive contributions of aryl and diazenyl radicals to film formation were identified, with the latter leading to the incorporation of azo bridges. Their relative contributions could be tuned through the electrografting conditions, enabling control over film growth and composition.<\/p><p>These principles were then extended to a ruthenium bis-terpyridine complex. The resulting Ru(tpy)\u2082 multilayers remained electrochemically active over a broad range of thicknesses, while their electronic properties were influenced by immobilization. Remarkably, the initially coordinatively saturated Ru(tpy)\u2082 complex displayed catalytic activity toward water oxidation after electrografting. These results highlight the role of film formation and molecular confinement in determining the properties and reactivity of functional molecular interfaces.<\/p><p><!-- notionvc: e4c86367-0ded-45ff-9d10-d00cb857da79 --><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>\ud83c\udf93 [THESIS DEFENSE] &#8211; Sara Helis will defend her PhD thesis: \ud83d\udd2c \u201cTailoring Functional Molecular Interfaces through Controlled Aryldiazonium Electrografting for Enhanced Reactivity\u201d \ud83d\udcc5 Friday 6 November 2026 at 09:15 &#8211; Facult\u00e9 des Sciences d\u2019Angers \/ Amphi L004 This thesis is labelled by EUR LUMOMAT This thesis is supervised by Prof. Tony Breton \u2013 MOLTECH-Anjou [&hellip;]<\/p>\n","protected":false},"author":7,"featured_media":10506,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[],"class_list":["post-10501","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-actualites"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.7 - 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